Bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate
Bis(4-tert-butylphenyl)iodonium triflate
CAS: 84563-54-2
Molecular Formula: C21H26F3IO3S
Bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate - Names and Identifiers
Bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate - Physico-chemical Properties
| Molecular Formula | C21H26F3IO3S |
| Molar Mass | 542.39 |
| Melting Point | 237°C(lit.) |
| Solubility | ethyl lactate: ~25% |
| Storage Condition | Inert atmosphere,Room Temperature |
Bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate - Risk and Safety
| Hazard Symbols | C - Corrosive |
| Risk Codes | 34 - Causes burns |
| Safety Description | S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | 3261 |
| WGK Germany | 3 |
| HS Code | 29319090 |
Bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate - Introduction
Bis(4-tert-butylphenyl)iodonium triflate (abbreviated TTBPI-Tf) is an organic compound with the following properties:
Nature:
-Appearance is white solid or crystalline powder.
-High thermal and chemical stability.
-Soluble in solvents, such as methanol, dimethylformamide, etc.
Use:
- TTBPI-Tf can be used as an electron-accepting and oxidizing agent in organic synthesis.
-In organic synthesis, it is often used to oxidize and functionalize benzene rings.
-In addition, it can also be used as a photosensitive material, fluorescent probe and photocatalyst.
Preparation Method:
-A common preparation method is to obtain bis (4-tert-butylphenyl) iodonium by reacting tert-butylbenzene iodide with hydrochloric acid catalyst, and then react with trifluoromethanesulfonic acid to obtain trifluoromethanesulfonate.
Safety Information:
- TTBPI-Tf is a strong oxidant, the operation should pay attention to safety.
-Avoid contact with combustibles and reducing agents to avoid fire or explosion.
-in the process of operation, need to wear protective gloves, goggles and other personal protective equipment.
-Follow regular chemical laboratory procedures and store and handle the compound properly. If in doubt, it is recommended to consult a professional.
Nature:
-Appearance is white solid or crystalline powder.
-High thermal and chemical stability.
-Soluble in solvents, such as methanol, dimethylformamide, etc.
Use:
- TTBPI-Tf can be used as an electron-accepting and oxidizing agent in organic synthesis.
-In organic synthesis, it is often used to oxidize and functionalize benzene rings.
-In addition, it can also be used as a photosensitive material, fluorescent probe and photocatalyst.
Preparation Method:
-A common preparation method is to obtain bis (4-tert-butylphenyl) iodonium by reacting tert-butylbenzene iodide with hydrochloric acid catalyst, and then react with trifluoromethanesulfonic acid to obtain trifluoromethanesulfonate.
Safety Information:
- TTBPI-Tf is a strong oxidant, the operation should pay attention to safety.
-Avoid contact with combustibles and reducing agents to avoid fire or explosion.
-in the process of operation, need to wear protective gloves, goggles and other personal protective equipment.
-Follow regular chemical laboratory procedures and store and handle the compound properly. If in doubt, it is recommended to consult a professional.
Last Update：2024-04-09 15:18:01
